3-7 July 2017
Africa/Johannesburg timezone

Mass-loading effect of graphene foam (GF) on the electrochemical performance of nickel phosphate as an electrode for supercapacitor application

4 Jul 2017, 11:30
20m
A403A (Engineering Building 51)

A403A

Engineering Building 51

Oral Presentation Track A - Division for Physics of Condensed Matter and Materials Physics of Condensed Matter and Materials 1

Speaker

Mr Abdulmajid A. Mirghni (UP)

Description

This work presents the effect of different contents of graphene foam (GF) on the electrochemical capacitance of nickel phosphate Ni3(PO4)2 nanorods as an electrode material for supercapacitor applications. Ni3(PO4)2 nanorods were synthesized via a hydrothermal method followed by different mass loading of graphene (30, 60, 90 and 120 mg, denoted as Ni3(PO4)2/30 mg GF, Ni3(PO4)2/60 mg GF, Ni3(PO4)2/90 mg GF and Ni3(PO4)2/120 mg GF, respectively. The electrochemical behavior of Ni3(PO4)2 and Ni3(PO4)2/GF nanorods composites were analyzed in a three-electrode cell using cyclic voltammetry (CV), galvanostatic charge–discharge (GCD) and electrochemical impedance spectroscopy (EIS) in a 6 M KOH electrolyte. The electrochemical tests showed that the specific capacitance increased with increasing the GF content up to 90 mg then decreased. The Ni3(PO4)2/90 mg GF exhibited the highest specific capacitance of 606 F g-1 (using CV curve) and 462 F g-1 (using CD curve) at 5 mV s-1 scan rate and 0.5 A g-1 current density respectively. The high specific capacitance is attributed to good crystallinity and synergetic interaction of the GF and Ni3(PO4)2 nanorods.

Apply to be<br> considered for a student <br> &nbsp; award (Yes / No)?

Yes

Main supervisor (name and email)<br>and his / her institution

Ncholu Manyala, ncholu.manyala@up.ac.za, University of Pretoria

Would you like to <br> submit a short paper <br> for the Conference <br> Proceedings (Yes / No)?

Yes

Level for award<br>&nbsp;(Hons, MSc, <br> &nbsp; PhD, N/A)?

PhD

Primary author

Mr Abdulmajid A. Mirghni (UP)

Co-authors

Mr Kabir O. Oyedotun (UP) Dr Moshawe J. Madito (UP) Prof. Ncholu Manyala (UP) Mrs Ndeye M. Ndiaye (UP) Dr Tshifhiwa M. Masikhwa (UP)

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