3-7 July 2017
Africa/Johannesburg timezone

Intermediate Valence behavior in the new ternary compound Yb<sub>13</sub>Pd<sub>40</sub>Sn<sub>31</sub>

4 Jul 2017, 10:00
20m
A403A (Engineering Building 51)

A403A

Engineering Building 51

Oral Presentation Track A - Division for Physics of Condensed Matter and Materials Physics of Condensed Matter and Materials 1

Speaker

Ms Redrisse Djoumessi Fobasso (University of Johannesburg)

Description

The new ternary intermetallic compound Yb13Pd40Sn31 was obtained as part of the investigation of the isothermal section of the Yb-Pd-Sn system at 600°C [1]. The polycrystalline sample was prepared by induction melting method in sealed tantalum crucible under a stream of pure argon gas. The powder x-ray pattern indicated that the sample crystallizes in a hexagonal structure, similar to hP168-Yb13Pd40Sn31 [1]. Magnetic susceptibility measurement depicted a strange and non-regular temperature dependence in applied magnetic field of 0.01 T. The inverse magnetic susceptibility does not obey Curie-Weiss law throughout the measured temperature range (400 K – 2 K).This behavior is unexpected for Yb in its magnetic Yb3+ state and suggests that the system is well described by the interconfiguration fluctuation (ICF) model, having an unstable valence for Yb ion. The temperature dependent electrical resistivity shows that the compound becomes superconducting below 2.3 K, however, there are some speculations about the bulk character of this superconductivity ground state. Specific heat analysis shows that the anomaly at 2.3 K survives even in 1 T but is completely suppressed in B = 4 T. As a most important discovery, we observe that, aside from the peak at Tsc, there is an enormous upturn in the Cp(T)/T vs T graph towards lowest temperature than can be assigned as a first thought to a form of nuclear entropy.

Main supervisor (name and email)<br>and his / her institution

Prof. Andre M. Strydom

University of Johannesburg

Level for award<br>&nbsp;(Hons, MSc, <br> &nbsp; PhD, N/A)?

MSc

Apply to be<br> considered for a student <br> &nbsp; award (Yes / No)?

Yes

Would you like to <br> submit a short paper <br> for the Conference <br> Proceedings (Yes / No)?

Yes

Primary author

Ms Redrisse Djoumessi Fobasso (University of Johannesburg)

Co-authors

Prof. Andre Strydom (University of Johannesburg) Dr Federica Gastaldo (University of Genova) Prof. Ivan Curlik (University of Prešov) Prof. Marian Reiffers (University of Prešov) Prof. Mauro Giovannini (University of Genova)

Presentation Materials

There are no materials yet.

Peer reviewing

Paper