3-7 July 2017
Africa/Johannesburg timezone

Thermal and electrical transport properties of Sm<sub>3</sub>Rh<sub>4</sub>Ge<sub>13</sub> compound

4 Jul 2017, 17:10
1h 50m
3rd and 4th floor passages (Engineering Building 51)

3rd and 4th floor passages

Engineering Building 51

Board: 14
Poster Presentation Track A - Division for Physics of Condensed Matter and Materials Poster Session 1

Speaker

Ms Sindisiwe Xhakaza (Highly Correlated Matter Research Group, Department of Physics, University of Johannesburg, South Africa)

Description

Polycrystalline samples of Sm3Rh4Ge13 compound was synthesized by arc melting the stoichometric quntities of respective purity elements. The compounds crystallize in the usual cubic structure, space group Pm ̅3n (#223) [1-2]. Our magnetic susceptibility measurements show antiferomagnetic behavour at low temperatures, at TN = 5 K, for Sm3Rh4Ge13. The high temperature data of the inverse magnetic susceptibility deviates from Curie-Weiss behaviour, and rather obey modified Curie-Weiss law. This work will focus on thermoelectric properties of the system where, our electrical resistivity data depict a semiconducting nature by virtue of a systematic negative coefficient of temperature dependance and overall values of resistivity that are not within the normal-metal range. The measured thermal transport properties values of Sm3Rh4Ge13 exhibit low thermal conductivity and fairly high and positive thermopower suggesting that the fermi surface in these materials is hole dominated.

Summary

Reference:
[1] J. L. Hodeau, J. Chenavas, M. Marezio, J. P. Remeika, Solid State Commun. 36 (1980) 839–845.
[2] R. Gumeniuk et al. Dalton Trans. 41 (2012) 6299–6309.

Level for award<br>&nbsp;(Hons, MSc, <br> &nbsp; PhD, N/A)?

MSc

Would you like to <br> submit a short paper <br> for the Conference <br> Proceedings (Yes / No)?

Yes

Apply to be<br> considered for a student <br> &nbsp; award (Yes / No)?

Yes

Main supervisor (name and email)<br>and his / her institution

Prof Andre Michael Strydom
amstrydom@uj.ac.za
University of Johannesburg

Primary author

Ms Sindisiwe Xhakaza (Highly Correlated Matter Research Group, Department of Physics, University of Johannesburg, South Africa)

Co-authors

Prof. Andre Strydom (University of Johannesburg) Dr Buyi Sondezi (University of Johannesburg)

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Peer reviewing

Paper