4-8 July 2016
Kramer Law building
Africa/Johannesburg timezone
<a href="http://events.saip.org.za/internalPage.py?pageId=10&confId=86">The Proceedings of SAIP2016</a> published on 24 December 2017

Enhanced photoluminescence emission from Dy <sup>3+</sup> and Tb<sup>3+</sup> activated lanthanum phosphovanadate

5 Jul 2016, 16:10
1h 50m
Kramer Law building

Kramer Law building

UCT Middle Campus Cape Town
Board: A.472
Poster Presentation Track A - Division for Physics of Condensed Matter and Materials Poster Session (1)

Speaker

Mr Selepe Joel Motloung (University of the Free State)

Please indicate whether<br>this abstract may be<br>published online<br>(Yes / No)

No

Apply to be<br> considered for a student <br> &nbsp; award (Yes / No)?

No

Abstract content <br> &nbsp; (Max 300 words)<br><a href="http://events.saip.org.za/getFile.py/access?resId=0&materialId=0&confId=34" target="_blank">Formatting &<br>Special chars</a>

Dysprosium and terbium doped lanthanum phosphovanadate (LaV0.25P0.75O4: Dy3+ and Tb3+) phosphor powders were synthesized by the solution combustion method. X-ray diffraction (XRD) was used investigate phase formation of the prepared phosphor powder. Scanning electron microscopy (SEM) images revealed that the prepared powder consisted of different shapes and sizes. Elemental composition was examined by energy dispersive x-ray spectroscopy (EDS), while the stretching mode frequencies were determined by Fourier transform infrared spectroscopy (FTIR). The band gap was estimated from the diffuse reflectance spectra. The excitation spectra of both dysprosium and terbium doped samples showed a strong broad band extending from 200 to 350 nm with the maximum at λ ≈ 274 nm. Photoluminescence emission spectra for dysprosium doped samples showed two peaks at 480 nm (4 F9/26 H13/2) and 573 nm (4 F9/26 H15/2) corresponding to Dy3+ emission while four emission peaks were observed for terbium doped samples at 490 nm (5 D27 F5), 544 nm (5 D27 F5), 586 nm (5 D27 F2) and 623nm (5 D27 F5) corresponding to transitions of Tb3+ ions. These photoluminescence results further revealed that the PL intensity increases with an increase in temperature.

Would you like to <br> submit a short paper <br> for the Conference <br> Proceedings (Yes / No)?

Yes

Main supervisor (name and email)<br>and his / her institution

Prof O.M Ntwaeaborwa
ntwaeb@ufs.ac.za
University of the Free State

Level for award<br>&nbsp;(Hons, MSc, <br> &nbsp; PhD, N/A)?

N/A

Primary author

Mr Selepe Joel Motloung (University of the Free State)

Co-authors

Dr Kamohelo George Tshabalala (University of the Free State) Prof. Odirileng Martin Ntwaeaborwa (University of the Free State) Dr Samy Shaat (Islamic University of Palestine)

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