3-7 July 2017
Africa/Johannesburg timezone

Effect of growth time of hydrothermally grown VO2 for supercapacitors applications

4 Jul 2017, 17:10
1h 50m
3rd and 4th floor passages (Engineering Building 51)

3rd and 4th floor passages

Engineering Building 51

Board: 10
Poster Presentation Track A - Division for Physics of Condensed Matter and Materials Poster Session 1

Speaker

Mrs Ndeye Maty Ndiaye (UP)

Description

In this work, we report the time-dependent synthesis of VO2 microspheres and nanosheets by hydrothermal method with a systematic improvement in physical and electrochemical properties such as specific surface area and specific capacitance at synthesis time of 6 h. VO2 microspheres and nanosheets were characterized by SEM, BET and XRD. The results show that variation of reaction time plays a crucial role in the transformation of samples morphology. VO2 microspheres synthesized within 4 h represents the intermediate reaction time between VO2 microsphere and nanosheets. VO2 grown at 6 h under the same synthesis conditions exhibited the highest specific capacitance of 485 F g-1 at a current density of 0.5 A g-1 in 6 M KOH electrolyte using Ni foam as a current collector and also showed excellent stability with ~ 98.5 % capacitance retention after 1000 cycles at a current density of 10 A g-1. Based on the above results, the VO2 nanosheets show a considerable potential as electrode materials for supercapacitor applications.

Level for award<br>&nbsp;(Hons, MSc, <br> &nbsp; PhD, N/A)?

PhD

Apply to be<br> considered for a student <br> &nbsp; award (Yes / No)?

Yes

Would you like to <br> submit a short paper <br> for the Conference <br> Proceedings (Yes / No)?

Yes

Main supervisor (name and email)<br>and his / her institution

Prof. Ncholu Manyala, Ncholu.Manyala@up.ac.za, University of Pretoria, Hatfield, Pretoria.

Primary authors

Prof. Ncholu Manyala (UP) Mrs Ndeye Maty Ndiaye (UP)

Co-authors

Prof. Aboubaker C Beye (UCAD) Prof. Balla Diop Ngom (UCAD) Dr Jack. Madito Madito (UP) Dr Julien K Dangbegnon (UP) Mr Kabir O. Oyedotun (UP) Dr Tshifhiwa Masikhwa (UP)

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