8-12 July 2019
Polokwane
Africa/Johannesburg timezone
Deadline for papers for the conference proceedings is 15 August 2019

Effect of neutron irradiation on the structural, electrical and optical properties evolution of RPLD VO<sub>2</sub> films

Not scheduled
2h
Protea The Ranch Hotel (Polokwane)

Protea The Ranch Hotel

Polokwane

Track B - Nuclear, Particle and Radiation Physics Poster Session 1

Speaker

Dr Itani Given Madiba (iThemba Laboratory for Accelerator Based Sciences)

Description

Vanadium dioxide (VO2) is explored as an active smart radiation device (SRD) for new type of thermal control material for space craft especially in small satellites such as CubeSats. Current space thermal control systems require heaters with an additional power penalty to maintain moderate spacecraft’s temperatures during extreme temperatures. Because its emissivity can be changed without electrical instruments or mechanical part, the use of VO2 based thin films decreases the request of spacecraft power budget. As an active smart radiator device, an ideal VO2 based nano-coatings should have a low emissivity at low temperatures to maintain the heat, whereas at high temperatures its emissivity should be high to dissipate the additional unnecessary heat [1,2]. In addition to their active thermal management properties, these VO2 coatings must exhibit deep space radiations hardness. while in outer space such coatings will be exposed to different cosmic radiation including neutrons. Because these radiations interact with the material in different ways, this contribution reports on the study of VO2 coatings properties subjected to neutron irradiation with typical energy and doses to space missions. The induced defects on the properties of VO2 thin films have been investigated using electrical, optical and structural measurements. Both Raman and the grazing incident angle X ray diffraction analysis show that no structural transformation is induced by neutron irradiation, although the grain size formation along the preferential orientation is affected. According to X-ray photoelectron spectroscopy, resistivity and work function measurements, the charge carrier (electron) concentration at room temperature decreases after irradiation. Taking into account that (i) fast neutron irradiation induced defects are mainly a series of Frenkel pairs defects, swelling and disordered regions in VO2 thin films without amorphization and (ii) resistivity and THz transmission measurements confirm that the characteristic semiconductor to metal transition of the VO2 films is preserved upon irradiation, we conclude that VO2 is an excellent candidate for thermal shielding and thermal management of small satellites. References 1.M. Benkahoul, M. Chaker, J. Margot, E. Haddad, R. Kruzelecky, B. Wong, W. Jamroz, P. Poinas, Sol. Energy Mater. Sol. Cells 95, 3504–3508 (2011). 2.E. Haddad, R. Kruzelecky, B. Wong, W. Jamroz, M. Soltani, M. Chaker, P. Poinas, M. Benkahoul, SAE Inc. 1, 2575–2587 (2009).

Apply to be<br> considered for a student <br> &nbsp; award (Yes / No)?

No

Level for award<br>&nbsp;(Hons, MSc, <br> &nbsp; PhD, N/A)?

N/A

Primary author

Dr Itani Given Madiba (iThemba Laboratory for Accelerator Based Sciences)

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