3-7 July 2023
University of Zululand
Africa/Johannesburg timezone
The Proceedings of SAIP2023 Published: 20 December 2023

O2 adsorption on PtSb2 (100) surface

6 Jul 2023, 14:00
20m
University of Zululand

University of Zululand

Oral Presentation Track F - Applied Physics Applied Physics

Speaker

Dr Samuel Mangwejane

Description

In order to understand the oxidation of the PtSb2 minerals by either weathering or exposure to air, we considered the adsorption of oxygen molecules on mineral surfaces. The adsorption properties will give more insight into the interaction of the oxygen with the atoms on the surface. Generally, minerals are exposed to atmospheric air during crushing or storage. It had been reported previously that oxidation depresses sulphide minerals, resulting in poor grade-recovery performance and the brittle nature of PtSb2 may result in difficulty of its recovery from such ores. The surface energy of (100) has been found to be 0.920 Jm-2 as compared to (110) 1.194 Jm-2 and (111) 0.939 Jm-2. We performed oxidation on the PtSb2 (100) surface where O2 was adsorbed in a peroxo, superoxide and Pt-O-O-Sb bridging on the surface Pt and Sb atoms.

Level for award;(Hons, MSc, PhD, N/A)?

N/A

Apply to be considered for a student ; award (Yes / No)? No

Primary authors

Dr Samuel Mangwejane Dr Peace Mkhonto (SAIP) Prof. Phuti Ngoepe (SAIP)

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Paper