3-7 July 2023
University of Zululand
Africa/Johannesburg timezone
The Proceedings of SAIP2023 Published: 20 December 2023

Optimization of deposition voltage for growth of CdZrS thin films for window layer of CdTe-based solar cell device application.

4 Jul 2023, 15:40
2h
University of Zululand

University of Zululand

Poster Presentation Track A - Physics of Condensed Matter and Materials Poster Session 1

Speaker

TSHEPO KARABO WILLIAM MOHAPI (UNIVERSITY OF THE FREE STATE)

Description

CdZrS thin films were synthesized by the two-electrode electrodeposition method at different growth voltages (1535-1570) mV with intervals of 5 mV on conductive glass substrate fluorine-doped thin oxide (FTO). Structural, optical, electrical, surface morphology, surface roughness, and elemental composition of the as-prepared and annealed CdZrS thin films were investigated by using X-ray diffraction (XRD), UV-vis spectrophotometry, photoelectrochemical cell analysis (PEC), scanning electron microscopy (SEM), scanning probe microscopy (SPM) and energy-dispersive X-ray spectroscopy (EDS) respectively. The structural characteristics revealed that the films have cubic and hexagonal mixed phases. Their energy band gap was found to change with the deposition voltage. PEC analysis verified that both the as-deposited and the annealed samples are p- and n-type conductivity. The surface morphology and roughness study demonstrates that the film completely covered the glass substrate and that the form, grain size, and morphology all altered with deposition cathode voltage. The elemental composition analysis confirmed the presence of Cd, Zr, and S in the films, and their percentage composition varied with deposition voltage. The overall analysis shows the addition of Zr in CdS thin films increased the band gap, and therefore, the prepared materials have potential application in p-n junction solar cells as a window (buffer) layer.

Level for award;(Hons, MSc, PhD, N/A)?

MSc

Apply to be considered for a student ; award (Yes / No)? Yes

Primary author

TSHEPO KARABO WILLIAM MOHAPI (UNIVERSITY OF THE FREE STATE)

Co-authors

Mr A.U. Yimamu (UFS) Dr K.G. Tshabalala (UFS) Dr S.J. Motloung (UFS)

Presentation Materials

There are no materials yet.

Peer reviewing

Paper