3-7 July 2023
University of Zululand
Africa/Johannesburg timezone
The Proceedings of SAIP2023 Published: 20 December 2023

Characterization of defects in ZnO implanted with Ar+ using positron annihilation technique.

6 Jul 2023, 14:20
20m
University of Zululand

University of Zululand

Oral Presentation Track A - Physics of Condensed Matter and Materials Physics of Condensed Matter and Materials Track 1

Speaker

Musawenkosi Khulu (University of Zululand)

Description

ZnO (wurtzite) samples were implanted with Ar+ ions to generate intrinsic defects within the ZnO samples at fluence range from 1 x 1015 to 3 x 1016 ions.cm-2. Doppler broadening of the annihilation curves were obtained to determine S-parameters which are used to characterize the defects. S-parameters are 0.35795, 0.35809 and 0.39025 for the lowest to the highest fluence, respectively. X-ray diffraction method was employed to determine any structural damage or phase change during the implantation. Positron annihilation spectroscopy shows the formation of anion point defects. Optical absorption measurements suggest the presence of F aggregate centres at 300.0 nm (4.14 eV). Theoretical calculations of the annihilation curves, based on local density approximation as well as generalized gradient approximation, were obtained. Theoretical results compare well with experimental results. Positron annihilation measurements are also correlated with optical absorption results on Ar+ ion implanted zinc oxide crystal.

Level for award;(Hons, MSc, PhD, N/A)?

MSc

Apply to be considered for a student ; award (Yes / No)? Yes

Primary author

Musawenkosi Khulu (University of Zululand)

Co-authors

Dr Morgan Madhuku (iThemba LABS) Prof. Thulani Jili (University of Zululand) Cebo Ndlangamandla (University of Zululand) Dr Phumlani Zipho Ngcobo (University of Zululand)

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