28 June 2015 to 3 July 2015
Africa/Johannesburg timezone
SAIP2015 Proceeding published on 17 July 2016

Embedding of noble metal nanoparticles and study of optical and photoluminescence properties induced by ion irradiation

2 Jul 2015, 09:40
20m
Oral Presentation Track A - Division for Physics of Condensed Matter and Materials DPCMM

Speaker

Dr Jai Prakash (Department of Physics, University of the Free State, (UFS), Bloemfontein, ZA 9300, South Africa)

Please indicate whether<br>this abstract may be<br>published online<br>(Yes / No)

Yes

Level for award<br>&nbsp;(Hons, MSc, <br> &nbsp; PhD, N/A)?

N/A

Main supervisor (name and email)<br>and his / her institution

Prof. H.C.Swart
Department of Physics, University of the Free State (UFS), Bloemfontein, ZA 9300, South Africa

Apply to be<br> considered for a student <br> &nbsp; award (Yes / No)?

No

Abstract content <br> &nbsp; (Max 300 words)<br><a href="http://events.saip.org.za/getFile.py/access?resId=0&materialId=0&confId=34" target="_blank">Formatting &<br>Special chars</a>

Recent advances in nanotechnology resulted in a new class of nanomaterials with optical as well as luminescence properties called noble metal fluorescent nanoparticles. These noble metal nanoparticles have shown potential applications in many fields like optical memory, catalysis and sensor technologies [1]. The present work reports on 150 keV Ar ion beam irradiation of thin Au film on polymer substrates including dewetting in thin film and subsequent formation of spherical Au nanoparticles that at a proper fluence eventually become embedded into the substrate [2]. Au nanoparticles embedded in and located on the surface were characterised and studied by scanning electron microscopy (SEM), atomic force microscopy (AFM), transmission electron microscopy (TEM) and Rutherford backscattering spectrometry (RBS) [3]. These Au nanoparticles exhibit the presence of absorption peaks in the visible regions due to the surface plasmon resonance (SPR) oscillations as investigated by UV-Vis spectroscopy. Photoluminescence study using the 325 nm He-Cd laser excitation will also be discussed.

References:
1. Li-Yi Chen, Chia-Wei Wang, Zhiqin Yuan, and Huan-Tsung Chang, Analytical Chemistry, 87 (2015) 216.
2. Jai Prakash, A. Tripathi, S. Gautam, K. H. Chae, V. Rigato, J. Tripathi, K. Asokan, Mat. Chem. Phys. 147 (2014) 920
3. Jai Prakash, A. Tripathi, V. Rigato, J.C.Pivin, Jalaj Tripathi, K.H.Chae, S.Gautam, P.Kumar, K. Asokan, D.K.Avasthi, , J. Phys.D: Appl. Phys. 44 (2011) 125302.

Acknowledgement: Author (JP) acknowledges the help and scientific discussions from Dr. D. K.Avasthi, Dr. A. Tripathi, and Dr. Pravin Kumar for providing LEIBF facility at IUAC, New Delhi.

Would you like to <br> submit a short paper <br> for the Conference <br> Proceedings (Yes / No)?

yes

Primary author

Dr Jai Prakash (Department of Physics, University of the Free State, (UFS), Bloemfontein, ZA 9300, South Africa)

Co-authors

Prof. H C Swart (Department of Physics, University of the Free State (UFS), Bloemfontein, ZA 9300, South Africa) Dr K Asokan (Inter University Accelerator Centre (IUAC), Aruna Asif Ali Marg, New Delhi 110067, India) Dr K H Chae (Advanced Analysis Center, Korea Institute of Science and Technology (KIST), Seoul 136e791, Republic of Korea) Prof. R E Kroon (Department of Physics, University of the Free State (UFS), Bloemfontein, ZA 9300, South Africa) Dr S Gautam (Advanced Analysis Center, Korea Institute of Science and Technology (KIST), Seoul 136e791, Republic of Korea) Dr V Rigato (INFN Laboratori Nazionali di Legnaro, Via Romea. 4, 35020 Legnaro, Padova, Italy) Dr Vinod Kumar (Department of Physics, University of the Free State (UFS), Bloemfontein, ZA 9300, South Africa)

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