28 June 2015 to 3 July 2015
Africa/Johannesburg timezone
SAIP2015 Proceeding published on 17 July 2016

Ultrafast photochromism in metal-organic complexes

2 Jul 2015, 10:00
20m
Oral Presentation Track C - Photonics Photonics

Speaker

Mr Xavier von Stein (Stellenbosch University)

Would you like to <br> submit a short paper <br> for the Conference <br> Proceedings (Yes / No)?

No

Level for award<br>&nbsp;(Hons, MSc, <br> &nbsp; PhD, N/A)?

Msc

Please indicate whether<br>this abstract may be<br>published online<br>(Yes / No)

No

Main supervisor (name and email)<br>and his / her institution

Prof. Heinrich Schwoerer
heso@sun.ac.za
Stellenbosch University

Apply to be<br> considered for a student <br> &nbsp; award (Yes / No)?

Yes

Abstract content <br> &nbsp; (Max 300 words)<br><a href="http://events.saip.org.za/getFile.py/access?resId=0&materialId=0&confId=34" target="_blank">Formatting &<br>Special chars</a>

Meriwether et al conducted the first thorough investigation of the photochromic properties of the metal dithizonates in 1965. Until recently however, the photochromism of metal-dithizonates have not been studied in the ultrafast regime (in the order of femto- to picoseconds). This study serves as a continuation of the prior research conducted by G.W. Bosman in 2012. A variety of metal dithizonates are investigated using a pump-probe spectroscopic technique, namely, transient absorption spectroscopy (TAS), to determine whether they display photochromism. Furthermore, using TAS will allow for speculation of the underlying mechanism that is responsible for the photochromic behavior.
What makes these molecules particularly interesting is that the photochromic mechanism is not yet confirmed (albeit it is thought that isomerisation plays a key role) and that these molecules can potentially be incorporated into molecular electronics.

Primary author

Mr Xavier von Stein (Stellenbosch University)

Co-authors

Dr Christine Steenkamp (Co-supervisor) Dr Gurthwin Bosman (Co-supervisor) Prof. Heinrich Schwoerer (Supervisor)

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