28 June 2015 to 3 July 2015
Africa/Johannesburg timezone
SAIP2015 Proceeding published on 17 July 2016

CZTS solar cell: A green energy source produced in a green way.

30 Jun 2015, 16:10
1h 50m
Board: A.318
Poster Presentation Track A - Division for Physics of Condensed Matter and Materials Poster1

Speaker

Mr Antonie Fourie (University of the Free State)

Level for award<br>&nbsp;(Hons, MSc, <br> &nbsp; PhD, N/A)?

MSc

Apply to be<br> considered for a student <br> &nbsp; award (Yes / No)?

Yes

Main supervisor (name and email)<br>and his / her institution

Prof JJ Terblans, UFS, terblansjj@ufs.ac.za

Would you like to <br> submit a short paper <br> for the Conference <br> Proceedings (Yes / No)?

Yes

Abstract content <br> &nbsp; (Max 300 words)<br><a href="http://events.saip.org.za/getFile.py/access?resId=0&materialId=0&confId=34" target="_blank">Formatting &<br>Special chars</a>

A solar cell can be produced by using low-cost, abundant and non-toxic constituent elements. This can be done using inexpensive production methods including electroplating and electron beam evaporation. It is possible to select the constituent elements as well as the chemicals used during the production to have as little as possible environmental impact. A micrometer thick layer of molybdenum evaporated onto soda-lime glass is used as a substrate, the glass can be replaced with a flexible substrate to produce a flexible solar cell. Cu2ZnSnS4 (CZTS) is used as the absorber layer of a solar cell because it is a p-type semiconductor with a bandgap of about 1.45 eV. A Cu-Zn-Sn precursor layer is also electrodeposited in one step using a deep eutectic solution consisting of choline chloride and urea. This type of ionic solution is classified as “green chemistry”, due to the low environmental impact of the chemicals involved. The Cu-Zn-Sn layer is deposited by electron beam evaporation. The CZTS layer is then formed by annealing it in a sulfur containing atmosphere. The rest of the solar cell is an n-type layer consisting of zinc oxide combined with either magnesium or sulfur to modify its conduction band offset, followed by a zinc sulfide window layer. Characterisation of the layers is done using X-ray diffraction, Auger electron spectroscopy, Scanning electron microscopy, X-ray photoelectron spectrometry. Preliminary results will be presented.

Please indicate whether<br>this abstract may be<br>published online<br>(Yes / No)

Yes

Primary author

Mr Antonie Fourie (University of the Free State)

Co-authors

Prof. Hendrik Swart (University of the Free State) Prof. JJ (Koos) Terblans (UFS)

Presentation Materials

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