28 June 2015 to 3 July 2015
Africa/Johannesburg timezone
SAIP2015 Proceeding published on 17 July 2016

A model describing two-exciton effects in photosynthetic light-harvesting systems

1 Jul 2015, 10:00
20m
Oral Presentation Track G - Theoretical and Computational Physics TCP

Speaker

Mr Johan Nöthling (University of Pretoria)

Please indicate whether<br>this abstract may be<br>published online<br>(Yes / No)

Yes

Apply to be<br> considered for a student <br> &nbsp; award (Yes / No)?

Yes

Abstract content <br> &nbsp; (Max 300 words)<br><a href="http://events.saip.org.za/getFile.py/access?resId=0&materialId=0&confId=34" target="_blank">Formatting &<br>Special chars</a>

In the light-harvesting apparatus of photosynthetic organisms, energy is transferred from captured photons to exciton states. These states, which are remarkably quantum in nature, are characterized by the sharing of an electronic excitation amongst different chromophore molecules. Energy can be passed coherently between two exciton states. Because of the presence of quantum coherence, energy can be transferred rapidly and very efficiently over large molecular distances; from the locus of photon capture to the reaction centre (where a spatial charge separation is achieved). In general, energy is transferred to the reaction centre so rapidly that only a single exciton exists in the light-harvesting system at a given time. Certain processes, however, like the annihilation of singlet excitation states by long-lasting triplet states, require a two-exciton description. We have set up a time-dependent, Redfield-type model that well-describes the time-evolution of single- and two-exciton states. This model will be discussed, as well as its application to real biological systems.

Level for award<br>&nbsp;(Hons, MSc, <br> &nbsp; PhD, N/A)?

MSc

Would you like to <br> submit a short paper <br> for the Conference <br> Proceedings (Yes / No)?

No

Main supervisor (name and email)<br>and his / her institution

Dr. Tjaart (T.P.J) Krüger
Tjaart.Kruger@up.ac.za
University of Pretoria

Primary author

Mr Johan Nöthling (University of Pretoria)

Co-authors

Dr Tjaart Krüger (University of Pretoria) Prof. Tomáš Mančal (Charles University)

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