4-8 July 2016
Kramer Law building
Africa/Johannesburg timezone
<a href="http://events.saip.org.za/internalPage.py?pageId=10&confId=86">The Proceedings of SAIP2016</a> published on 24 December 2017

Internal quantum efficiency and energy transfer processes in Ce3+ co-doped ZrO2: Eu3+ nanorods

8 Jul 2016, 11:30
20m
4B (Kramer Law building)

4B

Kramer Law building

UCT Middle Campus Cape Town
Oral Presentation Track A - Division for Physics of Condensed Matter and Materials Division for Physics of Condensed Matter and Materials (2)

Speaker

Dr Iorkyaa Ahemen (University of the Free State-Qwaqwa Campus)

Please indicate whether<br>this abstract may be<br>published online<br>(Yes / No)

yes

Apply to be<br> considered for a student <br> &nbsp; award (Yes / No)?

No

Level for award<br>&nbsp;(Hons, MSc, <br> &nbsp; PhD, N/A)?

N/A

Would you like to <br> submit a short paper <br> for the Conference <br> Proceedings (Yes / No)?

yes

Abstract content <br> &nbsp; (Max 300 words)<br><a href="http://events.saip.org.za/getFile.py/access?resId=0&materialId=0&confId=34" target="_blank">Formatting &<br>Special chars</a>

Cerium co-doped ZrO2: Eu3+ nanorods was synthesized by a simple chemical dehydration route and their structural, morphological and optical properties were investigated. Structural studies revealed mixed-phases of monoclinic and tetragonal Bravis lattices. Nanorods of different dimensions were observed on the scanned images. Excitation and absorption spectra revealed the dominance of the Eu3+ - O2- charge transfer states band over the intraconfigurational lines of the activator ion. A broad emission band with center maximum at 465 nm is attributed to both Ce3+ ion and the host band emissions. Electronic transitions in the range 500 nm to 650 nm are assigned to the Eu3+ ion. No significant energy transfer was observed because concentration quenching process dominated the energy transfer process. The internal quantum efficiency decreased with increasing Ce3+ concentration.

Main supervisor (name and email)<br>and his / her institution

Prof. Dejene B.F.; DejeneBF@ufs.ac.za; University of The Free State Qwaqwa Campus Phuthaditjhaba,South Africa

Primary author

Dr Iorkyaa Ahemen (University of the Free State-Qwaqwa Campus)

Co-author

Prof. Francis B. Dejene (University of the Free State-Qwaqwa Campus)

Presentation Materials