28 June 2015 to 3 July 2015
Africa/Johannesburg timezone
SAIP2015 Proceeding published on 17 July 2016

Effect of pH on ZnO nanostructures prepared by chemical bath method

3 Jul 2015, 09:40
20m
Oral Presentation Track A - Division for Physics of Condensed Matter and Materials DPCMM

Speaker

Dr Lehlohonolo Koao (UFS (Qwa Qwa)

Level for award<br>&nbsp;(Hons, MSc, <br> &nbsp; PhD, N/A)?

PHD

Apply to be<br> considered for a student <br> &nbsp; award (Yes / No)?

No

Abstract content <br> &nbsp; (Max 300 words)<br><a href="http://events.saip.org.za/getFile.py/access?resId=0&materialId=0&confId=34" target="_blank">Formatting &<br>Special chars</a>

ZnO powders were prepared by chemical bath method varying the pH using ammonia solution. The effect of pH of the precursor on the structure, morphology, optical and luminescence properties of ZnO nanostructures were investigated. The X-ray diffraction (XRD) patterns of the ZnO nanostructures correspond to the various planes of a single hexagonal ZnO phase. It was observed that the diffraction peaks increase in intensity with an increase in pH. The estimated average grain sizes calculated using the XRD spectra were found to be in the order of 38 ± 1 nm. It was observed that the estimated average grain sizes increases slightly with an increase in pH. The surface morphology study revealed that the grains are flakes-likes at low pH (< 6) but flower-like at high pH (12). The UV-Vis spectra showed a red shift with an increase in pH. The band gap energy of ZnO was found to decrease but the luminescence intensities increase with an increase in pH values. The maximum luminescence intensity was found at pH of 12.

Main supervisor (name and email)<br>and his / her institution

Koao L.F.

Please indicate whether<br>this abstract may be<br>published online<br>(Yes / No)

Yes

Would you like to <br> submit a short paper <br> for the Conference <br> Proceedings (Yes / No)?

Yes

Primary author

Dr Lehlohonolo Koao (UFS (Qwa Qwa)

Co-authors

Prof. Birhanu Dejene (UFS (Qwa Qwa)) Prof. Hendrik Swart (UFS (Bloemfontein))

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